分析例
有機溶剤保持時間表
|
充填剤No.
|
||||||
---|---|---|---|---|---|---|---|
①
|
②
|
③
|
④
|
⑤
|
⑥
|
||
Hydrocarbons
|
n-Pentane
|
0.97
|
1.01
|
4.16
|
2.36
|
0.67
|
0.80
|
n-Hexane
|
1.21
|
1.20
|
8.48
|
4.38
|
0.72
|
0.92
|
|
n-Heptane
|
1.66
|
1.79
|
18.10
|
8.40
|
0.84
|
1.15
|
|
n-Octane
|
2.55
|
2.89
|
39.30
|
16.47
|
1.06
|
1.55
|
|
n-Nonane
|
4.24
|
5.19
|
81.40
|
31.52
|
1.51
|
2.29
|
|
n-Decane
|
7.47
|
9.15
|
-
|
65.50
|
2.41
|
3.63
|
|
iso-Pentane
|
0.93
|
0.85
|
3.72
|
2.19
|
0.66
|
0.77
|
|
iso-Octane
|
1.57
|
1.85
|
22.19
|
10.56
|
0.79
|
1.13
|
|
Methyl cyclopentane
|
1.52
|
1.44
|
8.65
|
5.05
|
0.81
|
1.05
|
|
Methyl cyclohexane
|
2.33
|
2.27
|
18.93
|
10.36
|
1.00
|
1.41
|
|
Cyclohexane
|
1.85
|
1.69
|
9.69
|
5.71
|
0.90
|
1.19
|
|
Alcohols
|
Methanol
|
4.18
|
1.44 *
|
1.17
|
0.95
|
1.32 *
|
1.15
|
Ethanol
|
5.07
|
0.99 *
|
1.89
|
1.41
|
1.54
|
1.25
|
|
n-Propanol
|
9.28
|
1.48 *
|
3.76
|
2.59
|
2.55
|
1.80
|
|
n-Butanol
|
18.34
|
2.43 *
|
8.07
|
5.17
|
4.66
|
2.87
|
|
iso-Propanol
|
4.97
|
1.14 *
|
2.85
|
2.04
|
1.49
|
1.28
|
|
iso-Butanol
|
12.84
|
1.99 *
|
6.64
|
4.45
|
3.38
|
2.29
|
|
sec-Butanol
|
8.83
|
1.76 *
|
6.05
|
3.85
|
2.40
|
1.84
|
|
tert-Butanol
|
4.58
|
1.28 *
|
4.37
|
2.73
|
1.36
|
1.28
|
|
iso-Amylalcohol
|
33.15
|
9.23 *
|
14.87
|
9.50
|
6.67
|
3.67
|
|
Cyclohexanol
|
110.11
|
9.51 *
|
37.29
|
24.19
|
23.17
|
9.03
|
|
Aromatic
hydrocarbons |
Benzene
|
3.59
|
3.23
|
9.57
|
6.01
|
1.77
|
1.69
|
Toluene
|
6.31
|
3.52
|
20.76
|
12.19
|
2.85
|
2.59
|
|
Ethylbenzene
|
10.49
|
5.97
|
39.99
|
21.29
|
4.61
|
3.96
|
|
p-Xylene
|
11.42
|
6.22
|
42.53
|
23.52
|
4.80
|
4.20
|
|
m-Xylene
|
11.42
|
6.28
|
42.53
|
23.52
|
5.00
|
4.20
|
|
o-Xylene
|
14.55
|
7.65
|
48.83
|
27.75
|
6.32
|
5.05
|
|
Styrene
|
19.16
|
7.77
|
46.52
|
27.05
|
9.65
|
6.07
|
|
p-Cymene
|
-
|
13.94
|
-
|
62.29
|
11.38
|
8.79
|
|
Chlorobenzene
|
15.26
|
6.37
|
31.19
|
19.45
|
7.70
|
4.84
|
|
o-Dichlorobenzene
|
87.54
|
20.65
|
95.74
|
62.97
|
33.09
|
14.79
|
|
Esters
|
Methyl acetate
|
2.18
|
1.69
|
3.33
|
2.27
|
1.13
|
1.16
|
Ethyl acetate
|
2.98
|
2.19
|
6.20
|
3.95
|
1.36
|
1.40
|
|
n-Propyl acetate
|
4.93
|
3.66
|
13.09
|
7.64
|
2.01
|
1.95
|
|
n-Butyl acetate
|
8.77
|
6.35
|
28.63
|
15.23
|
3.40
|
3.01
|
|
iso-Propyl acetate
|
3.32
|
2.71
|
10.15
|
5.59
|
1.44
|
1.51
|
|
iso-Butyl acetate
|
6.45
|
5.22
|
23.72
|
11.87
|
2.47
|
2.39
|
|
iso-Amyl acetate
|
12.31
|
9.17
|
53.52
|
24.07
|
4.57
|
3.99
|
|
Methylmethacrylate
|
5.29
|
3.27
|
11.76
|
7.09
|
2.37
|
2.05
|
|
Methyl acrylate
|
3.53
|
2.16
|
5.99
|
3.93
|
1.70
|
1.52
|
|
Ethyl acrylate
|
5.60
|
3.16
|
11.07
|
6.37
|
2.23
|
1.95
|
|
Chlorinated
hydrocarbons |
Dichloromethane
|
2.64
|
1.80
|
3.44
|
2.28
|
1.50
|
1.34
|
Trichloroethylene
|
4.58
|
2.30
|
9.81
|
6.36
|
2.24
|
1.91
|
|
1,1,1-Trichloroethane
|
2.78
|
1.88
|
8.24
|
5.05
|
1.39
|
1.41
|
|
Tetrachloroethylene
|
6.33
|
4.02
|
20.52
|
11.64
|
2.85
|
2.65
|
|
1,2-Dichloroethane
|
5.68
|
2.30
|
6.89
|
4.77
|
3.08
|
2.05
|
|
1,1,2-Trichloroethane
|
16.54
|
4.24
|
16.53
|
10.51
|
9.70
|
4.47
|
|
1,1,2,2-Tetrachloroethane
|
13.69
|
9.53
|
43.08
|
27.03
|
44.69
|
13.16
|
|
Carbon tetrachloride
|
4.68
|
1.78
|
8.89
|
5.37
|
1.36
|
1.43
|
|
Chloroform
|
4.80
|
1.53
|
5.73
|
3.92
|
2.45
|
1.68
|
|
cis-1,2-Dichloroethylene
|
3.97
|
1.65
|
5.12
|
3.31
|
2.05
|
1.66
|
|
1,1-Dichloroethane
|
2.60
|
1.47
|
4.92
|
3.28
|
1.34
|
1.28
|
|
Freon 11
|
0.94
|
1.22
|
3.58
|
2.26
|
0.70
|
0.65
|
|
Freon 12
|
0.92
|
0.91
|
1.44
|
1.29
|
0.78
|
0.52
|
|
Freon 114
|
0.92
|
0.96
|
2.50
|
1.04
|
0.71
|
0.54
|
|
Cellosolves
|
Methyl cellosolve
|
25.59
|
6.91
|
6.93
|
4.62
|
5.79 *
|
3.12
|
Cellosolve
|
26.66
|
3.88 *
|
13.00
|
7.74
|
7.65 *
|
4.01
|
|
Butyl cellosolve
|
-
|
10.91 *
|
58.67
|
29.00
|
23.26 *
|
10.60
|
|
Methyl cellosolve acetate
|
25.13
|
9.47
|
26.68
|
15.11
|
9.57
|
5.16
|
|
Cellosolve acetate
|
27.53
|
12.46
|
50.31
|
25.40
|
12.55
|
6.80
|
|
Ether
|
Ethyl ether
|
1.17
|
1.16
|
3.45
|
2.05
|
0.71
|
0.85
|
Aldehydes
|
Acetaldehyde
|
1.43
|
1.09
|
1.32
|
1.03
|
0.78
|
0.83
|
Acrolein
|
2.37
|
1.52
|
2.41
|
1.75
|
1.15
|
1.09
|
|
Oxides
|
Dioxane
|
7.68
|
5.19
|
9.79
|
6.64
|
3.21
|
2.41
|
Tetrahydrofuran
|
3.36
|
2.03
|
5.63
|
3.99
|
1.31
|
1.40
|
|
Amides
|
Dimethylformamide
|
59.00 *
|
23.77 *
|
12.76
|
9.33
|
13.89 *
|
8.00 *
|
Acrylamide
|
?
|
?
|
24.49
|
23.83
|
?
|
?
|
|
Ketones
|
Acetone
|
2.31
|
1.76
|
2.73
|
1.89
|
1.07
|
1.09
|
MEK
|
3.63
|
2.63
|
5.55
|
3.43
|
1.48
|
1.43
|
|
MIBK
|
7.22
|
5.64
|
19.57
|
10.04
|
2.50
|
2.32
|
|
Cyclohexanone
|
36.36
|
18.09
|
36.17
|
21.96
|
12.27
|
7.84
|
|
2-Hexanone
|
12.06
|
7.41
|
24.35
|
13.99
|
3.14
|
2.85
|
|
2-Methylcyclohexanone
|
47.54
|
20.65
|
64.70
|
38.38
|
11.45
|
7.91
|
|
Nitriles Acrylonitrile
|
4.18
|
2.14
|
2.19
|
1.81
|
2.01
|
1.48
|
|
Acetonitrile
|
4.44
|
2.24
|
3.04
|
2.29
|
2.16
|
1.47
|
|
Nitriles
|
Acrylonitrile
|
4.18
|
2.40
|
2.19
|
1.81
|
2.01
|
1.48
|
Acetonitrile
|
4.44
|
2.24
|
3.04
|
2.29
|
2.16
|
1.47
|
|
Acids
|
Acrylic acid
|
-
|
-
|
6.32
|
6.08
|
-
|
20.29
|
Methacrylic acid
|
-
|
2.24 *
|
12.72
|
10.64
|
-
|
32.33
|
|
Acetic acid
|
-
|
3.31 *
|
3.48
|
3.78
|
22.83 *
|
8.06
|
|
n-Propionic acid
|
-
|
5.45 *
|
7.32
|
6.92
|
40.15 *
|
14.46
|
|
iso-Butyric acid
|
-
|
7.16 *
|
12.72
|
10.65
|
49.22 *
|
18.51
|
|
n-Butyric acid
|
-
|
9.02 *
|
14.84
|
12.66
|
72.74 *
|
26.08
|
|
Inorganic
|
Water
|
10.41 *
|
1.23 *
|
0.83
|
?
|
4.31 *
|
1.51 *
|
* : テーリングピーク
注) ① BX-10 60/80 Glass 3m×3mm I.D. 85ºC N2 35mL/min
② BX-100 60/80 Glass 3m×3mm I.D. 110ºC N2 35mL/min
③ Gaskuropack 54 60/80 Glass 2m×3mm I.D. 180ºC N2 35mL/min
④ Gaskuropack 55 60/80 Glass 2m×3mm I.D. 180ºC N2 35mL/min
⑤ Unisole 30T 5% Uniport HP 80/100 Glass 2m×3mm I.D. 70ºC N2 29mL/min
⑥ Unisole F-200 30/60 Glass 3m×3mm I.D. 110ºC N2 30mL/min